pith. sign in

arxiv: 2408.07477 · v2 · pith:KOTM3TVFnew · submitted 2024-08-14 · ❄️ cond-mat.supr-con · cond-mat.mtrl-sci

Ternary superhydrides under pressure of Anderson's theorem: Near-record superconductivity in (La,Sc)H₁₂

classification ❄️ cond-mat.supr-con cond-mat.mtrl-sci
keywords superconductinganomalyformationobservedsuperconductivitysuperhydridesternaryaccount
0
0 comments X
read the original abstract

Lanthanum-hydrogen system and its derivatives remain among the most promising for achieving room-temperature superconductivity. In this study, we examined the formation of ternary lanthanum-scandium superhydrides at pressures up to 220 GPa. The primary product of the LaSc alloy's reaction with hydrogen is newly discovered cubic (La,Sc)H$_{12}$, demonstrating clear superconducting transition in all six channels of the van der Pauw scheme below 244-248 K. In this compound with an unusually large unit cell volume, virtually no magnetoresistance was observed in fields up to 68 Tesla. Synthesized samples of (La,Sc)H$_{12}$ demonstrate pronounced superconducting diode and SQUID-like effects at a record high temperature of 233 K. Furthermore, our analysis revealed the formation of lower hexagonal polyhydrides (La,Sc)H$_{6-7}$, which could potentially account for the anomaly in electrical resistance observed near 274 K. This anomaly between 265-290 K also appears in the radio-frequency transmission measurements and may be of a superconducting nature.

This paper has not been read by Pith yet.

discussion (0)

Sign in with ORCID, Apple, or X to comment. Anyone can read and Pith papers without signing in.