Sum Rules for Multi-Photon Spectroscopy of Ions in Finite Symmetry
classification
⚛️ physics.atm-clus
cond-matphysics.chem-ph
keywords
ionsmodelsrulessymmetrytransitionscasecharacterizingcombine
read the original abstract
Models describing one- and two-photon transitions for ions in crystalline environments are unified and extended to the case of parity-allowed and parity- forbidden p-photon transitions. The number of independent parameters for characterizing the polarization dependence is shown to depend on an ensemble of properties and rules which combine symmetry considerations and physical models.
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