A simple semiclassical approach to Kramers' problem
classification
❄️ cond-mat.stat-mech
physics.chem-phquant-ph
keywords
equationkramerssemiclassicalapproachbrowniancalculatecorrectiondescribes
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We show that Wigner-Leggett-Caldeira equation for Wigner phase space distribution function which describes the quantum Brownian motion of a particle in a force field in a high temerature, Ohmic environment can be identified as a semiclassical version of Kramers' equation. Based on an expansion in powers of $\hbar$ we solve this equation to calculate the semiclassical correction to Kramers' rate.
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