Intensity of Two-Photon Absorption Transitions for Ni2+ in MgO
classification
⚛️ physics.atm-clus
cond-mat.softphysics.chem-phquant-ph
keywords
configurationmodelobtainedsymmetrytransitionstwo-photonabsorptionadapted
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The parity-allowed two-photon transitions between the ground state 3A2(T2) of the configuration 3d8 in cubical symmetry and the excited states of the same configuration are obtained via a simple model. This model is developed in a symmetry adapted framework by using second-order mechanisms and ionic wave-functions. It is applied to the recent experimental results obtained by McClure and co-workers for Ni2+ in MgO.
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