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arxiv: 0808.2906 · v2 · submitted 2008-08-21 · ❄️ cond-mat.mes-hall · cond-mat.soft· physics.bio-ph· quant-ph

Enhanced quantum entanglement in the non-Markovian dynamics of biomolecular excitons

classification ❄️ cond-mat.mes-hall cond-mat.softphysics.bio-phquant-ph
keywords bathquantumentanglementexcitonsslowbiomolecularenvironmentmarkovian
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We show that quantum coherence of biomolecular excitons is maintained over exceedingly long times due to the constructive role of their non-Markovian protein-solvent environment. Using a numerically exact approach, we demonstrate that a slow quantum bath helps to sustain quantum entanglement of two pairs of Forster coupled excitons, in contrast to a Markovian environment. We consider the crossover from a fast to a slow bath and from weak to strong dissipation and show that a slow bath can generate robust entanglement. This persists to surprisingly high temperatures, even higher than the excitonic gap and is absent for a Markovian bath.

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