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arxiv: cond-mat/0209332 · v1 · pith:DDV62XKGnew · submitted 2002-09-13 · ❄️ cond-mat.soft · cond-mat.stat-mech· physics.bio-ph· physics.chem-ph· q-bio.BM

Raft Instability of Biopolymer Gels

classification ❄️ cond-mat.soft cond-mat.stat-mechphysics.bio-phphysics.chem-phq-bio.BM
keywords gelsattractionbiopolymerbreakdownonsagertheoryanisotropicapply
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Following recent X-ray diffraction experiments by Wong, Li, and Safinya on biopolymer gels, we apply Onsager excluded volume theory to a nematic mixture of rigid rods and strong ``$\pi/2$'' cross-linkers obtaining a long-ranged, highly anisotropic depletion attraction between the linkers. This attraction leads to breakdown of the percolation theory for this class of gels, to breakdown of Onsager's second-order virial method, and to formation of heterogeneities in the form of raft-like ribbons.

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