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Positional information as a universal predictor of freezing

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arxiv 2105.13616 v1 pith:TKNYEOBG submitted 2021-05-28 cond-mat.stat-mech cond-mat.mtrl-scicond-mat.softphysics.chem-phphysics.data-an

classification cond-mat.stat-mechcond-mat.mtrl-scicond-mat.softphysics.chem-phphysics.data-an
keywords mathrmmathsffreezinginformationpositionalacrossanalysisdiscussed
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abstract

Variation of positional information, measured by the two-body excess entropy $\mathsf{S}_\mathrm{2}$, is studied across the liquid-solid equilibrium transition in a simple two-dimensional system. Analysis reveals a master relation between $\mathsf{S}_\mathrm{2}$ and the freezing temperature $T_{\mathrm{f}}$, from which a scaling law is extracted: $-\mathsf{S}_\mathrm{2}\sim |T_{\mathrm{f}} - T| ^{-1/3}$. Theoretical and practical implications of the observed universality are discussed.

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