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Superconductivity in the parent infinite-layer nickelate NdNiO$_2$
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abstract
We report evidence for superconductivity with onset temperatures up to 11 K in thin films of the infinite-layer nickelate parent compound NdNiO$_2$. A combination of oxide molecular-beam epitaxy and atomic hydrogen reduction yields samples with high crystallinity and low residual resistivities, a substantial fraction of which exhibit superconducting transitions. We survey a large series of samples with a variety of techniques, including electrical transport, scanning transmission electron microscopy, x-ray absorption spectroscopy, and resonant inelastic x-ray scattering, to investigate the possible origins of superconductivity. We propose that superconductivity could be intrinsic to the undoped infinite-layer nickelates but suppressed by disorder due to its nodal order parameter, a finding which would necessitate a reconsideration of the nickelate phase diagram. Another possible hypothesis is that the parent materials can be hole doped from randomly dispersed apical oxygen atoms, which would suggest an alternative pathway for achieving superconductivity.
Forward citations
Cited by 3 Pith papers
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Observation of Electride-like $s$ States Coexisting with Correlated $d$ Electrons in NdNiO$_2$
In NdNiO2, the β pocket is shown to be dominated by interstitial s states with negligible Nd 5d/4f contribution, confirming electride-like behavior.
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In-Plane Ni-O-Ni Bond Angles as Structural Fingerprints of Superconductivity in Layered Nickelates: Effects of Pressure, Strain, Layering, and Correlations
The in-plane Ni-O-Ni bond angle in layered nickelates tracks the experimental superconducting Tc dome under pressure and strain, suggesting it as a structural fingerprint.
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Spin-glass state in nickelate superconductors
Infinite-layer nickelate superconductors show a spin-glass magnetic state with an onset temperature several times Tc, and its strength depends on the substrate while Tc does not.
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