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Fully ab-initio all-electron calculation of dark matter--electron scattering in crystals with evaluation of systematic uncertainties

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arxiv 2306.14944 v1 pith:KEWYL7FT submitted 2023-06-26 hep-ph astro-ph.COcond-mat.mtrl-sciphysics.comp-ph

classification hep-phastro-ph.COcond-mat.mtrl-sciphysics.comp-ph
keywords darkall-electronscatteringtransfersab-initiobasiscalculationgtrsim
verification ladder T0 review T1 audit T2 compute T3 formal
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abstract

We calculate target-material responses for dark matter--electron scattering at the \textit{ab-initio} all-electron level using atom-centered gaussian basis sets. The all-electron effects enhance the material response at high momentum transfers from dark matter to electrons, $q\gtrsim \mathcal{O}\left({10\ \alpha m_e}\right)$, compared to calculations using conventional plane wave methods, including those used in QEDark; this enhances the expected event rates at energy transfers $E \gtrsim 10$~eV, especially when scattering through heavy mediators. We carefully test a range of systematic uncertainties in the theory calculation, including those arising from the choice of basis set, exchange-correlation functional, number of unit cells in the Bloch sum, $\mathbf{k}$-mesh, and neglect of scatters with very high momentum transfers. We provide state-of-the-art crystal form factors, focusing on silicon and germanium. Our code and results are made publicly available as a new tool, called Quantum Chemistry Dark (``QCDark'').

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Cited by 5 Pith papers

Reviewed papers in the Pith corpus that reference this work. Sorted by Pith novelty score. Full citation record

  1. First-principles upper bounds on dark matter-electron scattering rates from condensed matter sum rules

    hep-ph 2026-08 conditional novelty 6.0 of 10

    Dark matter-electron scattering rates in isotropic materials are bounded from above by a universal expression depending only on plasma frequency, mass density, and static dielectric function.

  2. Direct Detection of Leptophobic Dark Matter with Electronic Collective Excitations

    hep-ph 2025-10 conditional novelty 6.0 of 10

    Leptophobic dark matter can excite plasmons in silicon through hadronic loops, and SENSEI data now constrain its nucleon cross section down to ~1e-31 cm^2 in the sub-MeV mass range.

  3. Electronic structure of liquid xenon in the context of light dark matter direct detection

    hep-ph 2025-02 conditional novelty 6.0 of 10

    Liquid xenon's effect on dark matter-electron scattering can be captured by atomic wave functions combined with a liquid density of states, shifting exclusion limits by up to a factor of two.

  4. Constraints on Sub-MeV Dark Matter from Solar Reflection with DAMIC-M

    hep-ex 2026-07 conditional novelty 5.5 of 10

    With ~1.3 kg-day of DAMIC-M skipper-CCD data, solar-reflected dark matter yields 90% CL limits on the DM-electron cross section reaching 3.16e-37 cm2 at 0.1 MeV for an ultralight mediator.

  5. Direct Detection and Cosmological Constraints of Dark Matter with Dark Dipoles

    hep-ph 2026-02 conditional novelty 5.0 of 10

    Cosmological and direct-detection data already exclude most sub-GeV dark-matter parameter space for dark-photon magnetic dipole interactions, with semiconductor detectors needed to probe the remaining electric-dipole ...

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