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Accurate and thermodynamically consistent hydrogen equation of state for planetary modeling with flow matching

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arxiv 2501.10594 v2 pith:YICZ2SGR submitted 2025-01-17 astro-ph.EP cond-mat.mtrl-scics.LGphysics.comp-ph

Accurate and thermodynamically consistent hydrogen equation of state for planetary modeling with flow matching

classification astro-ph.EP cond-mat.mtrl-scics.LGphysics.comp-ph
keywords hydrogenstateaccurateequationapproachconsistentdenseentropy
verification ladder T0 review T1 audit T2 compute T3 formal T4 reserved
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Accurate determination of the equation of state of dense hydrogen is essential for understanding gas giants. Currently, there is still no consensus on methods for calculating its entropy, which play a fundamental role and can result in qualitatively different predictions for Jupiter's interior. Here, we investigate various aspects of entropy calculation for dense hydrogen based on ab initio molecular dynamics simulations. Specifically, we employ the recently developed flow matching method to validate the accuracy of the traditional thermodynamic integration approach. We then clearly identify pitfalls in previous attempts and propose a reliable framework for constructing the hydrogen equation of state, which is accurate and thermodynamically consistent across a wide range of temperature and pressure conditions. This allows us to conclusively address the long-standing discrepancies in Jupiter's adiabat among earlier studies, demonstrating the potential of our approach for providing reliable equations of state of diverse materials.

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  1. A Denser Hydrogen Inferred from First-Principles Simulations Challenges Jupiter's Interior Models

    astro-ph.EP 2025-01 unverdicted novelty 6.0

    First-principles simulations find denser hydrogen at planetary conditions, implying lower bulk metallicity for Jupiter.